Preheat the oven to 325 degrees and line muffin tins with parchment paper (6.5X6.5 size).

In a large bowl, toss flour, baking powder, baking soda, and fine sea salt. Set aside.

Melt butter in a large saucepan over medium heat and whisk in Dutch process cocoa powder and cook for about a minute.

Remove the saucepan from the heat and stir in both sugars.

Add in coffee, buttermilk , eggs and vanilla beans and whisk until smooth.

Pour the chocolate mixture into the flour mixture and stir until combined.

Add chopped chocolate and stir into the batter.

Divide the batter between 10 jumbo muffin cavities. Fill any unused cavities halfway full with water for even baking.

Bake for about 25-26 minutes or until there are just a few moist crumbs picked up with a toothpick.

Let the muffins cool on a baking rack for 15 minutes to set. Say Grace and enjoy!